This is a single-edition Charlie Rhodes with a Sweet Caporal 350/30 back. There are 10 other advertising backs that appear with Rhodes which gives this pose 11 unique player/back combinations in the original 1909-11 T206 set.
Charlie "Dusty" Rhodes was a 5'7", 180lb, right-handed pitcher from Kansas who played 3 years in the majors with 2 different clubs. He finished his career with a 7-11 record, 3.46 ERA, 76 strikeouts, and a 1.28 WHIP. He pitched in 26 games (started 20 games) throughout his career and pitched a total of 143 innings. He died in 1918 at the age of 33.